Visible-Light-Driven H2 Generation from Water and CO2 Conversion by Using a Zwitterionic Cyclometalated Iridium(III) Complex

From light comes hydrogen: Photosensitizer [Ir(4‐CF3bt)2(Hbpdc)] behaves as a very active promoter towards H2 evolution from water when irradiated with visible light (see figure). A remarkable selective‐photoreduction for CO2 was also achieved.

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Bibliographic Details
Published inChemistry : a European journal Vol. 17; no. 46; pp. 12891 - 12895
Main Authors Yuan, Yong-Jun, Yu, Zhen-Tao, Chen, Xiao-Yu, Zhang, Ji-Yuan, Zou, Zhi-Gang
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 11.11.2011
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
Chemistry
CO2 reduction
hydrogen production
iridium
visible light
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Summary:From light comes hydrogen: Photosensitizer [Ir(4‐CF3bt)2(Hbpdc)] behaves as a very active promoter towards H2 evolution from water when irradiated with visible light (see figure). A remarkable selective‐photoreduction for CO2 was also achieved.
Bibliography:ArticleID:CHEM201102147
National Science Foundation of China - No. 20901038
National Basic Research Program of China - No. 2007CB613301
ark:/67375/WNG-0FSSF772-Q
Nature Science Foundation of Jiangsu Province - No. BK2008028
istex:9FFE41EC3A67718CDA4E6E3DC19BFD7F2BA05635
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201102147