Preparation and Crystal Structure of MnBiSe2I

Black single crystals of MnBiSe2I were obtained by the reaction of stoichiometric amounts of Mn, Bi, BiI3, and Se at 600 °C for 7 days. The compound crystallizes in the monoclinic system, space group C2/m, with a = 13.428(2), b = 4.112(1), c = 10.130(2) Å, β = 90.97(2)°, and Z = 4. The crystal struc...

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Published inZeitschrift für anorganische und allgemeine Chemie (1950) Vol. 631; no. 8; pp. 1439 - 1441
Main Authors Pfitzner, Arno, Zabel, Manfred, Rau, Franz
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.06.2005
WILEY‐VCH Verlag
Subjects
Bismuth
Crystal structure
Iodine
Manganese
Selenium
Sulfosalts
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Summary:Black single crystals of MnBiSe2I were obtained by the reaction of stoichiometric amounts of Mn, Bi, BiI3, and Se at 600 °C for 7 days. The compound crystallizes in the monoclinic system, space group C2/m, with a = 13.428(2), b = 4.112(1), c = 10.130(2) Å, β = 90.97(2)°, and Z = 4. The crystal structure refinement based on 849 reflections converged at R = 0.0380 and wR2 = 0.0916, respectively. MnBiSe2I forms a layer structure consisting of MnSe6 octahedra, MnSe2I4 octahedra, and BiSe3+2 pyramids.
Bibliography:Dedicated to Professor Gerd Becker on the Occasion of 65th Birthday
ArticleID:ZAAC200500072
istex:411D4D917CA57702A33E6B312D3F4F2949CD17A9
ark:/67375/WNG-F31SBKFR-F
th
Dedicated to Professor Gerd Becker on the Occasion of 65
Birthday
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.200500072