Synthesis of 2-substituted 2-arylmalonates via tricarbonylchromium complexes
Tricarbonylchromium complexes 1 react with monosubstituted malonic acid esters 2 in DMSO at room temperature in the presence of KOtBu to give the complexes 3. After oxidative demetalation, the appropriate aryl derivatives 4 are obtained in moderate to good overall yields. Diastereoselective arylatio...
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Published in | Journal für praktische Chemie, Chemiker-Zeitung Vol. 339; no. 3; pp. 261 - 265 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
HEIDELBERG
JOHANN AMBROSIUS BARTH VERLAG
01.01.1997
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Subjects | |
Online Access | Get more information |
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