Influence of the electron concentration on the superconducting properties of the spinel system Li1-yTi2O4
In the spinel system Li1‐y Ti2O4 the Li content was reduced by oxidative extraction by means of a solution of I2 as well as Br2 in CH3CN or by oxygen. The extraction is associated with a transition of Ti3+ to Ti4+: the system is Li1‐y Ti3+1‐yTi4+1+y O4. Consequently, with increasing y the charge car...
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Published in | Annalen der Physik Vol. 505; no. 8; pp. 685 - 694 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Leipzig
WILEY-VCH Verlag
1993
WILEY‐VCH Verlag |
Subjects | |
Online Access | Get full text |
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Summary: | In the spinel system Li1‐y Ti2O4 the Li content was reduced by oxidative extraction by means of a solution of I2 as well as Br2 in CH3CN or by oxygen. The extraction is associated with a transition of Ti3+ to Ti4+: the system is Li1‐y Ti3+1‐yTi4+1+y O4. Consequently, with increasing y the charge carrier concentration decreases from the starting value of 0.5 electrons/Ti ion for LiTi2O4. The extraction proceeds in two steps. At the beginning, the Ti2O4 framework remains intact and the transition to superconductivity increases with decreasing charge carrier concentration to a maximal value of 13.2 K. Separated by a two‐phase region for medium extraction levels for higher y values, a Li depleted material of approximate composition Li0.3Ti2O4 is obtained. The crystal structure of Li0.3Ti2O4 can be deduced from the original spinel lattice by a partial Ti migration from 16d to 16c and 8 a sites (space group Fd3m). Consequently, the Ti2O4 framework of Li0.3Ti2O4 is disconnected and the material is no longer superconducting. |
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Bibliography: | istex:C2854D22B84C5A4E907275AC1D7D822211DAF99B ArticleID:ANDP19935050803 Deutsche Forschungsgemeinschaft ark:/67375/WNG-7VZWFV0D-W |
ISSN: | 0003-3804 1521-3889 |
DOI: | 10.1002/andp.19935050803 |