VS2 Nanotubes Containing Organic-Amine Templates from the NT-VOx Precursors and Reversible Copper Intercalation in NT-VS2

Softly, softly: VS2 nanotubes (see electron micrograph, layer separation 1.6 nm) are prepared from vanadium oxide nanotubes by a “chimie douce” process. The VS2 nanotubes are remarkably stable; the corresponding bulk compound is unstable unless it is intercalated with alkali‐metal atoms. The nanotub...

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Published inAngewandte Chemie International Edition Vol. 44; no. 2; pp. 262 - 265
Main Authors Therese, Helen Annal, Rocker, Frank, Reiber, Andreas, Li, Jixue, Stepputat, Michael, Glasser, Gunnar, Kolb, Ute, Tremel, Wolfgang
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 27.12.2004
WILEY‐VCH Verlag
Subjects
Amines - chemistry
Copper - chemistry
nanotubes
Nanotubes - chemistry
Organometallic Compounds - chemistry
Oxygen - chemistry
sol-gel processes
Sulfur - chemistry
Sulfur - metabolism
template synthesis
vanadium
Vanadium - chemistry
Vanadium - metabolism
Vanadium Compounds - chemical synthesis
Vanadium Compounds - chemistry
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Summary:Softly, softly: VS2 nanotubes (see electron micrograph, layer separation 1.6 nm) are prepared from vanadium oxide nanotubes by a “chimie douce” process. The VS2 nanotubes are remarkably stable; the corresponding bulk compound is unstable unless it is intercalated with alkali‐metal atoms. The nanotubes reversibly intercalate copper with high capacity and thus could serve as precursors for conductors or contacts in electronic circuitry.
Bibliography:This work was supported by the Bundesministerium für Bildung und Forschung (BMBF) and by the Deutsche Forschungsgemeinschaft (DFG). NT=nanotube.
ark:/67375/WNG-HK0BN23W-6
ArticleID:ANIE200461326
istex:B70700982EF8A106A1171CCDBB0CB161624D9303
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200461326