Synthesis of Optically Pure 2,2′-Dimercurio-1,1′-binaphthyl Compounds: Catalysis of Diels−Alder Reactions of O-Ethyl Crotonthioate

Optically pure 2,2′‐bis(chloromercurio)‐1,1′‐binaphthyl, 2,2′‐bis(trifluoroacetatomercurio)‐1,1′‐binaphthyl, and 2,2′‐bis(trifluoromethanesulfonatomercurio)‐1,1′‐binaphthyl compounds have been synthesized. The dimercurio compounds show catalytic activity in the asymmetric Diels−Alder reactions with...

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Published inEuropean journal of organic chemistry Vol. 2000; no. 16; pp. 2901 - 2903
Main Authors Oh, Taeboem, Lopez, Patricia, Reilly, Michael
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 01.08.2000
WILEY‐VCH Verlag GmbH
Wiley
Subjects
Asymmetric catalysis
Chemistry
Chemistry, Organic
Lewis acids
Mercury
Pericyclic reactions
Physical Sciences
Science & Technology
pericyclic reactions
mercury
Lewis acids
CHEMISTRY
asymmetric catalysis
MULTIDENTATE LEWIS-ACIDS
CYCLOPENTADIENE
ACTIVE 2,2'-DIHALO-1,1'-BINAPHTHYLS
MULTIPLE COORDINATION
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Summary:Optically pure 2,2′‐bis(chloromercurio)‐1,1′‐binaphthyl, 2,2′‐bis(trifluoroacetatomercurio)‐1,1′‐binaphthyl, and 2,2′‐bis(trifluoromethanesulfonatomercurio)‐1,1′‐binaphthyl compounds have been synthesized. The dimercurio compounds show catalytic activity in the asymmetric Diels−Alder reactions with O‐ethyl crotonthioate.
Bibliography:ark:/67375/WNG-G1DKDRDQ-X
ArticleID:EJOC2901
istex:CA23775430AD0533EAAAB89E67BCDD8669F9521F
ISSN:1434-193X
1099-0690
DOI:10.1002/1099-0690(200008)2000:16<2901::AID-EJOC2901>3.0.CO;2-0