On the Hydrolysis of tBu2Ge(OEt)2: Supramolecular Self Assembly in the Solid State of 2 tBu2Ge(OH)2, (tBu2GeOH)2O, and H2O

The hydrolysis of tBu2Ge(OEt)2 is described. Depending on the amount of water used either tBu2Ge(OH)2 (1) or a mixture of the latter and (tBu2GeOH)2O (2) were obtained. A cocrystallate consisting of 2tBu2Ge(OH)2, (tBu2GeOH)2O and water was the subject of a single crystal X‐ray diffraction study. In...

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Published inEuropean journal of inorganic chemistry Vol. 2000; no. 5; pp. 939 - 941
Main Authors Beckmann, Jens, Jurkschat, Klaus, Schürmann, Markus
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 01.05.2000
WILEY‐VCH Verlag GmbH
Subjects
Germanium
Germanol
Hydrogen bonds
X-ray structure
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Summary:The hydrolysis of tBu2Ge(OEt)2 is described. Depending on the amount of water used either tBu2Ge(OH)2 (1) or a mixture of the latter and (tBu2GeOH)2O (2) were obtained. A cocrystallate consisting of 2tBu2Ge(OH)2, (tBu2GeOH)2O and water was the subject of a single crystal X‐ray diffraction study. In the solid state the individual molecules are connected by hydrogen bonds giving rise to the formation of a polymeric double chain ribbon.
Bibliography:ark:/67375/WNG-8BNSX5J1-6
ArticleID:EJIC939
istex:5DDC4ED39B60D2090513AD1150F00FDC36585993
ISSN:1434-1948
1099-0682
DOI:10.1002/(SICI)1099-0682(200005)2000:5<939::AID-EJIC939>3.0.CO;2-3