Structural properties and ionic conductivities of CuCr1-xVxS2 solid solutions

In the Cu(1 – x)CrxVS system CuCr1–xVxS2 solid solutions isostructural with CuCrS2 and Cu3VS4 were found by replacement of Cr by V up to x = 0.20. The oxidation states of Cr and V were determined from structural data and paramagnetic susceptibility measurements. The CuCr1–xVxS2 solid solutions were...

Full description

Saved in:
Bibliographic Details
Published inphysica status solidi (b) Vol. 236; no. 1; pp. 29 - 33
Main Authors Almukhametov, R. F., Yakshibayev, R. A., Gabitov, E. V., Abdullin, A. R., Kutusheva, R. M.
Format Journal Article
LanguageEnglish
Published Berlin WILEY-VCH Verlag 01.03.2003
WILEY‐VCH Verlag
Subjects
61.10.Nz
66.30.Hs
Online AccessGet full text

Cover

More Information
Summary:In the Cu(1 – x)CrxVS system CuCr1–xVxS2 solid solutions isostructural with CuCrS2 and Cu3VS4 were found by replacement of Cr by V up to x = 0.20. The oxidation states of Cr and V were determined from structural data and paramagnetic susceptibility measurements. The CuCr1–xVxS2 solid solutions were found to have mixed electronic and Cu+‐cationic conductivity. Copper cationic conductivity increases with increasing unit cell size.
Bibliography:ark:/67375/WNG-DW2FGDG1-8
ArticleID:PSSB200301413
istex:AA1C25DB5C8628BAE25F4E0E7E9E07CA0982D05D
ISSN:0370-1972
1521-3951
DOI:10.1002/pssb.200301413