1,3-DIPOLAR CYCLOADDITION OF CS2 TO THE COORDINATED AZIDE IN THE CYCLOPALLADATED [Pd(bzan)(μ-N3)]2. CRYSTAL AND MOLECULAR STRUCTURE OF DI(μ-N,S-1,2,3,4-THIATRIAZOLE-5-THIOLATE)BIS[(BENZYLIDENEANILINE-C2,N)PALLADIUM(II)]

The compound [Pd(bzan)(μ-N 3 )] 2 1, bzan = benzylideneaniline, was prepared from [Pd(bzan) (μ-OOCCH 3 )] 2 by an anion exchange reaction. The 1,3-dipolar cycloaddition of carbon disulfide to the bridged coordinated azide in the cyclometallated compound 1 was investigated. The species resulting from...

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Bibliographic Details
Published inJournal of coordination chemistry Vol. 53; no. 2; pp. 163 - 172
Main Authors Santana, Anderson Martinez, Mauro, Antonio Eduardo, De Almeida, Eduardo Tonon, Netto, Adelino Vieira de Godoy, Klein, Stanlei Ivair, Santos, Regina Helena de Almeida, Zóia, Jussara Ramos
Format Journal Article
LanguageEnglish
Published Taylor & Francis Group 01.04.2001
Subjects
Azido
Carbon disulfide
Cycloaddition
Cyclopalladated
Infrared spectroscopy
X-ray diffraction
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Summary:The compound [Pd(bzan)(μ-N 3 )] 2 1, bzan = benzylideneaniline, was prepared from [Pd(bzan) (μ-OOCCH 3 )] 2 by an anion exchange reaction. The 1,3-dipolar cycloaddition of carbon disulfide to the bridged coordinated azide in the cyclometallated compound 1 was investigated. The species resulting from this reaction, di(μ-N,S-1,2,3,4-thiatriazol-5-thiolate)bis [(benzylidene-aniline)palladium(II)] 2, was characterized by IR spectroscopy and X-ray diffraction. The compound 2 is a dimer containing two [Pd(benzylideneaniline)] moieties connected by two vicinal bridging N,S-1,2,3,4-thiatriazole-5-thiolate anions in a square-planar coordination geometry for the palladium atoms.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958970108022610