Hydrogen Bonds in Cellulose and Cellulose Derivatives

• Published in: Polysaccharides pp. 89 - 118
• Format: Book Chapter
• Language: English
• Published: United Kingdom CRC Press 2004; Taylor & Francis Group
• Subjects: Food & beverage technology; Organic chemistry; Pharmaceutical technology; IR Spectrum; Ma 13C NMR Spectrum; Common Hydrogen Bonds; Intramolecular Hydrogen Bonds; Ma 13C NMR; Interchain Hydrogen Bonds; Solid State CP; Cellulose Ii; Intermolecular Hydrogen Bonds; Intramolecular Hydrogen Bonding Formation; IR Band; Cellulose Ia; Amorphous Cellulose; Anhydroglucose Unit; Peak Tops; Chemical Shifts; Solution NMR; C3 Position; IR Absorption Band; Hydrogen Bonds; Native Cellulose; Intra-and Intermolecular Hydrogen Bonds; Inter-and Intramolecular Hydrogen Bonds; Noncrystalline Regions; Cellulose Derivatives
• ISBN: 9780824754808; 0824754808
• DOI: 10.1201/9781420030822-7

The native biopolymer assembly has been shown to be a complex process involving two separate but integrated steps of polymerization and crystallization [1,2]. In particular, cellulose has shown to be assembled by a macromolecular complex of enzymes located on the cell surface. Nature has designed an efficient system for regulating the molecular weight, crystallinity, size, and shape of the nanostructure of cellulose (called cellulose microfibrils). Then the microfibrils are self-assembled to form cell walls maintaining tree-frame structure. In this manner, cellulose molecules biosynthesized at angstrom scale assemble to be microfibrils at nanoscale, and the microfibrils assemble to be cell walls at micronscale, then they scale up with growing (Fig. 1). Hydrogen bonds are no doubt a major interaction to stabilize this hierarchical architecture of higher plants. Therefore considering hydrogen bonds of cellulose requires in your mind a picture of the size (angstrom, nano, or micron) of the subject that you are looking at.