Frontispiece: Design and Syntheses of Three Novel Carbonate Halides: Cs3Pb2(CO3)3I, KBa2(CO3)2F, and RbBa2(CO3)2F

Carbonate Halides Three new carbonate halides, Cs3Pb2(CO3)3I (CPCI), KBa2(CO3)2F (KBCF), and RbBa2(CO3)2F (RBCF) are reported by Y. Yang, Z. Yang, S. Pan et al. in their Full Paper on page 2944 ff. CPCI features a 2D layered structure, which, owing to the arrangement of CO3 units and the stereoactiv...

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Bibliographic Details
Published inChemistry : a European journal Vol. 22; no. 9
Main Authors Liu, Lili, Yang, Yun, Dong, Xiaoyu, Zhang, Bingbing, Wang, Ying, Yang, Zhihua, Pan, Shilie
Format Journal Article
LanguageEnglish
Published Weinheim Blackwell Publishing Ltd 24.02.2016
Wiley Subscription Services, Inc
Subjects
Birefringence
Cations
Chemistry
crystal structures
density functional calculations
Design
Displays
Divalent cations
Fluorides
Halides
Honeycomb construction
Lead
physical chemistry
X-ray diffraction
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Summary:Carbonate Halides Three new carbonate halides, Cs3Pb2(CO3)3I (CPCI), KBa2(CO3)2F (KBCF), and RbBa2(CO3)2F (RBCF) are reported by Y. Yang, Z. Yang, S. Pan et al. in their Full Paper on page 2944 ff. CPCI features a 2D layered structure, which, owing to the arrangement of CO3 units and the stereoactive Pb2+, displays moderate birefringence. KBCF and RBCF adopt a honeycomb‐like framework. Through comparison of these structures with other carbonate fluorides, it is illustrated that the quantity and distribution of O atoms and the position of divalent cations play essential roles in determining the arrangement of CO3 groups.
Bibliography:istex:7BBE4125431A2FDEC6FFF3940128E01F27ABF235
ark:/67375/WNG-9B1GDJ7V-K
ArticleID:CHEM201680962
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201680962