Convergent access to ketones, vinyl esters and vinyl bromides by a tin-free radical addition-intramolecular hydrogen atom transfer

Xanthate-mediated intermolecular radical addition, hydrogen atom transfer and sulfonyl radical elimination have been efficiently combined in a new convergent synthesis of ketones and substituted olefins.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 9; no. 6; pp. 778 - 779
Main Authors Ouvry, G, Zard, SZ
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2003
Royal Society of Chemistry
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
SULFONES
CARBON
BONDS
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Summary:Xanthate-mediated intermolecular radical addition, hydrogen atom transfer and sulfonyl radical elimination have been efficiently combined in a new convergent synthesis of ketones and substituted olefins.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/b212841a