One-step process to form a nickel-based/carbon nanofoam composite supercapacitor electrode using Na2SO4 as an eco-friendly electrolyte

• Published in: RSC advances Vol. 6; no. 19; pp. 1592 - 15928
• Main Authors: Della Noce, R, Eugénio, S, Boudard, M, Rapenne, L, Silva, T. M, Carmezim, M. J, Donne, S. W, Montemor, M. F
• Format: Journal Article
• Language: English
• Published: Royal Society of Chemistry 01.01.2016
• Subjects: Chemical Sciences; Material chemistry
• ISSN: 2046-2069
• DOI: 10.1039/c5ra22046g

In this work, NiO x is anodically electrodeposited onto carbon nanofoam (CNF) to form a composite electrode devoted to supercapacitor applications. The use of NiSO 4 as precursor in electrodeposition results in the formation of NiO and NiOOH species, as confirmed by XPS analysis, by means of a one-step anodic process. The presence of both NiO and NiOOH suggests the existence of pseudocapacitance, as observed in MnO 2 and RuO 2 materials. By employing Na 2 SO 4 , an eco-friendly electrolyte, the resulting composite delivers a specific capacitance of 150 F g −1 at 1 A g −1 considering the total mass of the electrode (deposit plus substrate). In addition, this composite electrode can operate in a very broad potential window, as high as 2.2 V, suggesting its application in high energy density electrochemical supercapacitors. Anodic electrodeposition of NiO x (NiO + NiOOH) onto carbon nanofoam forming a supercapacitor electrode. The resulting composite electrode operates at 2.2 V in Na 2 SO 4 aqueous medium.