Evidence of the intercalative redox polymerization of ethylenedioxythiophene into V2O5; achievement of highly conducting poly(3,4-ethylenedioxythiophene)/V2O5 nanohybrids

We have established a novel method of inserting poly(3,4-ethylenedioxythiophene) (PEDOT) between the layers of V2O5 using a soft process of intercalation. The reaction takes place with the in situ polymerization of EDOT within the framework of crystalline V2O5 with different nominal EDOT/V2O5 ratios...

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Bibliographic Details
Published inActive and passive electronic components Vol. 27; no. 4; pp. 229 - 236
Main Authors MURUGAN, A. V, KWON, C. W, HWANG, S. J, DELVILLE, M. H, PORTIER, J, CAMPET, G
Format Journal Article
LanguageEnglish
Published Abingdon Taylor and Francis 01.12.2004
Hindawi Publishing Corporation
Subjects
Applied sciences
Chemical Sciences
Electronics
Exact sciences and technology
Material chemistry
Materials
Microelectronic fabrication (materials and surfaces technology)
Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices
Conducting material
Fourier transform spectroscopy
Electrical conductivity
Redox polymerization
Chemical structure
Polymer
Nano-hybrids
X ray diffraction
Hybrid composite
Thin film
Intercalation compound
Infrared spectrometry
Microelectronic fabrication
Experimental result
Transmission electron microscopy
Vanadium oxide
Nanocomposite
High conductivity
Intercalative redox polymerization
PEDOT
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Summary:We have established a novel method of inserting poly(3,4-ethylenedioxythiophene) (PEDOT) between the layers of V2O5 using a soft process of intercalation. The reaction takes place with the in situ polymerization of EDOT within the framework of crystalline V2O5 with different nominal EDOT/V2O5 ratios. The hybrids PEDOT/V2O5 exhibit a high electrical conductivity.
ISSN:0882-7516
DOI:10.1080/08827510310001648852