Interaction between phases in the liquid-gas system1

• Published in: Journal of experimental and theoretical physics Vol. 123; no. 1; pp. 134 - 267
• Main Authors: Berry, R.S, Smirnov, B.M
• Format: Journal Article
• Language: English
• Published: Springer 01.07.2016
• Subjects: Thermodynamics
• ISSN: 1063-7761; 1090-6509
• DOI: 10.1134/S1063776116070153

This work analyzes the equilibrium between a liquid and a gas over this liquid separated by an interface. Various gas forms exist inside the liquid: dissolved gas molecules attached to solvent molecules, free gas molecules, and gaseous bubbles. Thermodynamic equilibrium is maintained between two phases; the first phase is the liquid containing dissolved and free molecules, and the second phase is the gas over the liquid and bubbles inside it. Kinetics of gas transition between the internal and external gas proceeds through bubbles and includes the processes of bubbles floating up and bubble growth as a result of association due to the Smoluchowski mechanism. Evolution of a gas in the liquid is considered using the example of oxygen in water, and numerical parameters of this system are given. In the regime under consideration for an oxygen-water system, transport of oxygen into the surrounding air proceeds through micron-size bubbles with lifetimes of hours. This regime is realized if the total number of oxygen molecules in water is small compared with the numbers of solvated and free molecules in the liquid.