Study on the Photodegradation Stability of Poly

A poly(butylene succinate-co-butylene adipate)/Ti[O.sub.2] (PBSA/Ti[O.sub.2]) nanocomposite was prepared by a melt- blending process. The effect of Ti[O.sub.2] nanoparticles on the photodegradation behaviors of the nanocomposite was investigated by transmission electron microscopy (TEM), differentia...

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Bibliographic Details
Published inJournal of chemistry Vol. 2019
Main Authors Cai, Lihai, Qi, Zhiguo, Xu, Jun, Guo, Baohua, Huang, Zhongyao
Format Journal Article
LanguageEnglish
Published John Wiley & Sons, Inc 31.03.2019
Subjects
Analysis
Butylene
Calorimetry
Infrared spectroscopy
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Summary:A poly(butylene succinate-co-butylene adipate)/Ti[O.sub.2] (PBSA/Ti[O.sub.2]) nanocomposite was prepared by a melt- blending process. The effect of Ti[O.sub.2] nanoparticles on the photodegradation behaviors of the nanocomposite was investigated by transmission electron microscopy (TEM), differential scanning calorimetry (DSC), Fourier-transform infrared spectroscopy (FT-IR), field- emission scanning electron microscopy (FE-SEM), rheological measurements, and mechanical tests. TEM images of the PBSA/Ti[O.sub.2] revealed that the Ti[O.sub.2] nanoparticles were well dispersed in the matrix without obvious aggregation. The FT-IR results indicated that the Ti[O.sub.2] nanoparticles can block high-energy ultraviolet (UV) light and reduce the degradation of the PBSA matrix. The viscosity analysis results indicated that the Ti[O.sub.2] nanoparticles inhibited the chain scission of PBSA matrix under irradiation. In addition, the surface of the PBSA/Ti[O.sub.2] films and their mechanical properties change less than that of untreated PBSA films during the photoaging process. The obtained results imply that the Ti[O.sub.2] nanoparticles can be considered as an efficient photodegradation-resistant additive to PBSA for reducing photodegradation.
ISSN:2090-9063
DOI:10.1155/2019/5036019