Probing C60

• Published in: Science (American Association for the Advancement of Science) Vol. 242; no. 4881; pp. 1017 - 1022
• Main Authors: CURL, R. F, SMALLEY, R. E
• Format: Journal Article
• Language: English
• Published: Washington, DC American Association for the Advancement of Science 18.11.1988; The American Association for the Advancement of Science
• Subjects: Analysis; Atomic and molecular clusters; Atomic and molecular physics; Atomic structure; Carbon compounds; Chemistry; Chemistry, Physical organic; Electronic structure; Exact sciences and technology; Physical organic chemistry; Physics; Studies of special atoms, molecules and their ions; clusters; Vaporization; Carbon Molecular ions; Supersonic beam; Photoelectron spectrum; Carbon Molecules; Atomic cluster; Review; Experimental study; Sputtering; Inorganic compound; Positive ion; Ultraviolet radiation; Electronic structure; Laser beam; Preparation; Mass spectrum; Negative ion
• ISSN: 0036-8075; 1095-9203
• DOI: 10.1126/science.242.4881.1017

Experiments involving the laser vaporization of graphite have indicated that one particular duster of carbon, C(60), is preeminently stable; this special stability may be evidence that C(60) can readily take the form of a hollow truncated icosahedron (a sort of molecular soccerball). If true, this structure for C(60) would be the first example of a spherical aromatic molecule. In fact, because of symmetry properties unique to the number 60, it may be the most perfecty spherical, edgeless molecule possible. Its rapid formation in condensing carbon vapors and its extreme chemical and photophysical stability may have far-reaching implications in a number of areas, particularly combustion science and astrophysics. For these reasons C(60) and other dusters of carbon have continued to be the subject of intense research. This article provides a short review of the many new experimental probes of the properties of C(60) and related carbon dusters.