Phosphorus‐Mediated MoS2 Nanowires as a High‐Performance Electrode Material for Quasi‐Solid‐State Sodium‐Ion Intercalation Supercapacitors

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 15; no. 4; pp. e1803984 - n/a
• Main Authors: Liu, Shude, Yin, Ying, Wu, Musheng, Hui, Kwan San, Hui, Kwun Nam, Ouyang, Chu‐Ying, Jun, Seong Chan
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 01.01.2019
• Subjects: Charge transfer; Density functional theory; Diffusion barriers; Diffusion coefficient; Diffusion layers; Doping; Electrical resistivity; electrochemical energy storage; Electrode materials; Electrodes; Energy storage; first‐principles calculations; Flux density; Intercalation; Ion charge; Ion diffusion; Manganese dioxide; Molybdenum disulfide; Nanotechnology; Nanowires; Phosphorus; phosphorus‐mediated MoS2; quasi‐solid‐state supercapacitors; Sodium; sodium‐ion intercalation; Supercapacitors; Vacancies
• ISSN: 1613-6810; 1613-6829
• DOI: 10.1002/smll.201803984

Molybdenum disulfide (MoS2) is a promising electrode material for electrochemical energy storage owing to its high theoretical specific capacity and fascinating 2D layered structure. However, its sluggish kinetics for ionic diffusion and charge transfer limits its practical applications. Here, a promising strategy is reported for enhancing the Na+‐ion charge storage kinetics of MoS2 for supercapacitors. In this strategy, electrical conductivity is enhanced and the diffusion barrier of Na+ ion is lowered by a facile phosphorus‐doping treatment. Density functional theory results reveal that the lowest energy barrier of dilute Na‐vacancy diffusion on P‐doped MoS2 (0.11 eV) is considerably lower than that on pure MoS2 (0.19 eV), thereby signifying a prominent rate performance at high Na intercalation stages upon P‐doping. Moreover, the Na‐vacancy diffusion coefficient of the P‐doped MoS2 at room temperatures can be enhanced substantially by approximately two orders of magnitude (10−6–10−4 cm2 s−1) compared with pure MoS2. Finally, the quasi‐solid‐state asymmetrical supercapacitor assembled with P‐doped MoS2 and MnO2, as the positive and negative electrode materials, respectively, exhibits an ultrahigh energy density of 67.4 W h kg−1 at 850 W kg−1 and excellent cycling stability with 93.4% capacitance retention after 5000 cycles at 8 A g−1. We propose an efficient P‐anion doping strategy to enhance the electrochemical performance of the MoS2 nanowires by increasing the number of electrochemically active sites, improving the electrical conductivity, and decreasing the energy barrier of Na+ ion diffusion. The P‐doped MoS2 delivers remarkable specific capacitance and rate capability. This study highlights the dominating role of P dopants in electrode materials for supercapacitors.