From a Si3-Cyclopropene to a Si3S-Bicyclo[1.1.0]butane to a Si3S-Cyclopropene to a Si3S2-Bicyclo[1.1.0]butane: Back-and-Forth, and In-Between
Compact and highly reactive bicyclo[1.1.0]butanes constitute one of the most fascinating classes of organic compounds. Furthermore, interplay of bicyclo[1.1.0]butanes with their valence isomers, such as buta‐1,3‐dienes and cyclobutenes, is among the fundamental pericyclic transformations in organic...
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Published in | Angewandte Chemie (International ed.) Vol. 54; no. 47; pp. 14118 - 14122 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
16.11.2015
WILEY‐VCH Verlag Wiley Subscription Services, Inc Wiley-VCH Verlag |
Edition | International ed. in English |
Subjects | |
Online Access | Get full text |
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Summary: | Compact and highly reactive bicyclo[1.1.0]butanes constitute one of the most fascinating classes of organic compounds. Furthermore, interplay of bicyclo[1.1.0]butanes with their valence isomers, such as buta‐1,3‐dienes and cyclobutenes, is among the fundamental pericyclic transformations in organic chemistry. Herein we report the back‐and‐forth interconversion between the cyclotrisilenes and thiatrisilabicyclo[1.1.0]butanes, allowing for the synthesis of novel representatives of such classes of highly reactive organometallics. The peculiar structural and bonding features of the newly synthesized compounds, as well as the mechanism of their isomerization, were verified both experimentally and computationally.
Back‐and‐forth and in‐between: The back‐and‐forth interconversion between the cyclotrisilenes and thiatrisilabicyclo[1.1.0]butanes is presented, allowing for the synthesis of highly reactive organometallic compounds. The peculiar structural and bonding features of the newly synthesized compounds, as well as their isomerization mechanism, are verified both experimentally and computationally. |
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Bibliography: | ArticleID:ANIE201506625 Ministry of Education, Science, Sports, and Culture of Japan Grant-in-Aid for Scientific Research - No. 15K05413; No. 23655027; No. 24245007; No. 90143164 SFedU - No. 213.01-2014/005 istex:F6309B27B0384599F2355D8505CAB8C8073D388E ark:/67375/WNG-BWJ449GB-8 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.201506625 |