Al2O3 Nanosheets Rich in Pentacoordinate Al3+ Ions Stabilize Pt-Sn Clusters for Propane Dehydrogenation

• Published in: Angewandte Chemie International Edition Vol. 54; no. 47; pp. 13994 - 13998
• Main Authors: Shi, Lei, Deng, Gao-Ming, Li, Wen-Cui, Miao, Shu, Wang, Qing-Nan, Zhang, Wei-Ping, Lu, An-Hui
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 16.11.2015; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Edition: International ed. in English
• Subjects: alumina; Catalysis; dehydrogenation; heterogeneous catalysis; nanosheets; Propane
• ISSN: 1433-7851; 1521-3773
• DOI: 10.1002/anie.201507119

In heterogeneous catalysis, supports play a crucial role in modulating the geometric and electronic structure of the active metal phase for optimizing the catalytic performance. A γ‐Al2O3 nanosheet that contains 27 % pentacoordinate Al3+ sites can nicely disperse and stabilize raft‐like Pt‐Sn clusters as a result of strong interactions between metal and support. Consequently, there are strong electronic interactions between the Pt and Sn atoms, resulting in an increase in the electron density of the Pt sites. When used in the propane dehydrogenation reaction, this catalyst displayed an excellent specific activity for propylene formation with >99 % selectivity, and superior anti‐coking and anti‐sintering properties. Its exceptional ability to maintain the high activity and stability at ultrahigh space velocities further showed that the sheet construction of the catalyst facilitated the kinetic transfer process. Stable and selective: γ‐Al2O3 nanosheets rich in pentacoordinate Al3+ ions can well disperse and stabilize raft‐like Pt‐Sn clusters, which results in an increase of the electron density of the Pt sites. This material catalyzes the conversion of propane into propylene with >99 % selectivity, and minimizes coke formation and sintering processes.