Asymmetric Supercapacitors Based on Graphene/MnO2 Nanospheres and Graphene/MoO3 Nanosheets with High Energy Density
Asymmetric supercapacitors with high energy density are fabricated using a self‐assembled reduced graphene oxide (RGO)/MnO2 (GrMnO2) composite as a positive electrode and a RGO/MoO3 (GrMoO3) composite as a negative electrode in safe aqueous Na2SO4 electrolyte. The operation voltage is maximized by c...
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Published in | Advanced functional materials Vol. 23; no. 40; pp. 5074 - 5083 |
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Main Authors | , , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Blackwell Publishing Ltd
01.10.2013
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Subjects | |
Online Access | Get full text |
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Summary: | Asymmetric supercapacitors with high energy density are fabricated using a self‐assembled reduced graphene oxide (RGO)/MnO2 (GrMnO2) composite as a positive electrode and a RGO/MoO3 (GrMoO3) composite as a negative electrode in safe aqueous Na2SO4 electrolyte. The operation voltage is maximized by choosing two metal oxides with the largest work function difference. Because of the synergistic effects of highly conductive graphene and highly pseudocapacitive metal oxides, the hybrid nanostructure electrodes exhibit better charge transport and cycling stability. The operation voltage is expanded to 2.0 V in spite of the use of aqueous electrolyte, revealing a high energy density of 42.6 Wh kg−1 at a power density of 276 W kg−1 and a maximum specific capacitance of 307 F g−1, consequently giving rise to an excellent Ragone plot. In addition, the GrMnO2//GrMoO3 supercapacitor exhibits improved capacitance with cycling up to 1000 cycles, which is explained by the development of micropore structures during the repetition of ion transfer. This strategy for the choice of metal oxides provides a promising route for next‐generation supercapacitors with high energy and high power densities.
Asymmetric supercapacitors with high energy density are fabricated using self‐assembled graphene/MnO2 as a positive electrode and graphene/MoO3 (GrMoO3) as a negative electrode in aqueous electrolyte. Choosing metal oxides with a large work function difference, the operating voltage is expanded to 2.0 V in spite of the use of the aqueous electrolyte, with a high energy density of 42.6 Wh kg−1 at a power density of 276 W kg−1 and a maximum capacitance of 307 F g−1. |
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Bibliography: | ark:/67375/WNG-BV5S0ZWL-8 Ministry of Education, Science and Technology (MEST) of Korea istex:88102FA696B732F01CC17F21197802323A7521BC ArticleID:ADFM201301851 |
ISSN: | 1616-301X 1616-3028 |
DOI: | 10.1002/adfm201301851 |