Potential and Limitations of Natural Chabazite for Selective Catalytic Reduction of NOx with NH3

• Published in: Chemie ingenieur technik Vol. 85; no. 5; pp. 632 - 641
• Main Authors: Günter, Tobias, Casapu, Maria, Doronkin, Dmitry, Mangold, Stefan, Trouillet, Vanessa, Augenstein, Timo, Grunwaldt, Jan-Dierk
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 01.05.2013; WILEY‐VCH Verlag
• Subjects: Chabazite; Exhaust gas catalysis; Hydrothermal stability; Structure-performance relations; Zeolites
• ISSN: 0009-286X; 1522-2640
• DOI: 10.1002/cite.201200182

The potential of the natural chabazite for the selective catalytic reduction (SCR) of NOx with NH3 is evaluated in the present work. Activity tests were performed under technically relevant reaction and temperature conditions for the fresh and hydrothermally aged catalysts. The natural chabazite before and after alkaline removal as well as after iron and copper addition were compared. The structural as well as surface and bulk properties were elucidated by a variety of complementary characterization techniques, i.e. XRD, XPS, EPR, BET, NH3‐TPD, ex situ and in situ XAS. The results indicate that an important facet for using the natural chabazite for the standard and fast SCR reactions is the removal of alkaline metals, which at the same time also leads to a partial change of the structure and the size of the iron‐containing particles. The performance and especially the hydrothermal stability can be further improved by copper addition. The potential of the natural chabazite for the selective catalytic reduction of NOx with NH3 is investigated. The natural chabazite before and after alkaline removal as well as after iron and copper addition were compared with respect to their performance under technically relevant reaction and temperature conditions in their fresh and hydrothermally aged state.