Catalytic Applications of Nano‐Fe‐[Phenyl‐Salicylaldimine‐Methylpyranopyrazole]Cl2 as a Schiff Base Complex and Nanostructured Catalyst for the Synthesis of Hexahydroquinolines

By the four‐component condensation reaction of benzaldehyde with ethyl acetoacetate, malononitrile, and hydrazine hydrate using FeCl2, a pyranopyrazole derivative was synthesized and then reacted with salicylaldehyde to give nano‐Fe‐[phenyl‐salicylaldimine‐methylpyranopyrazole]Cl2 (nano‐[Fe‐PSMP]Cl2...

Full description

Saved in:
Bibliographic Details
Published inJournal of the Chinese Chemical Society (Taipei) Vol. 64; no. 12; pp. 1496 - 1502
Main Authors Goudarziafshar, Hamid, Moosavi‐Zare, Ahmad Reza, Saki, Khadijeh, Abdolmaleki, Mehdi
Format Journal Article
LanguageEnglish
Published Weinheim Wiley‐VCH Verlag GmbH & Co. KGaA 01.12.2017
Wiley Subscription Services, Inc
Subjects
Benzaldehyde
Catalysis
Catalysts
Chemical synthesis
Hexahydroquinoline
Imines
Iron chlorides
Malononitrile
Multicomponent
Nano‐[Fe‐PSMP]Cl2
Schiff base complex
Online AccessGet full text

Cover

More Information
Summary:By the four‐component condensation reaction of benzaldehyde with ethyl acetoacetate, malononitrile, and hydrazine hydrate using FeCl2, a pyranopyrazole derivative was synthesized and then reacted with salicylaldehyde to give nano‐Fe‐[phenyl‐salicylaldimine‐methylpyranopyrazole]Cl2 (nano‐[Fe‐PSMP]Cl2). The prepared nano‐Schiff base complex was successfully used as an efficient catalyst for the synthesis of hexahydroquinolines. Nano‐Fe‐[phenyl‐salicylaldimine‐methylpyranopyrazole]Cl2 (nano‐[Fe‐PSMP]Cl2) is reported as a nano‐Schiff base complex and efficient catalyst for the synthesis of hexahydroquinolines.
ISSN:0009-4536
2192-6549
DOI:10.1002/jccs.201700211