Extending the Second‐Generation Phosphorus–Nitrogen PN3‐Pincer Ligand Family through Ligand Post‐Modification

A series of air‐stable nickel complexes containing triazine‐based PN3P‐pincer ligands were synthesized and fully characterized. Complex 3 contains a de‐aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post‐modification strategy, the Me‐PN3P*NiCl complex (3) coul...

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Bibliographic Details
Published inJournal of the Chinese Chemical Society (Taipei) Vol. 65; no. 1; pp. 60 - 64
Main Authors Huang, Mei‐Hui, Hu, Jinsong, Huang, Kuo‐Wei
Format Journal Article
LanguageEnglish
Published Weinheim Wiley‐VCH Verlag GmbH & Co. KGaA 01.01.2018
Wiley Subscription Services, Inc
Subjects
Coordination chemistry
Coordination compounds
Ligand post‐modification
Ligands
Nickel
Nitrogen
Pincer complex
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Summary:A series of air‐stable nickel complexes containing triazine‐based PN3P‐pincer ligands were synthesized and fully characterized. Complex 3 contains a de‐aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post‐modification strategy, the Me‐PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P‐pincer nickel complexes. A series of air‐stable nickel complexes containing triazine‐based PN3‐pincer ligands were synthesized and fully characterized. With a post‐modification strategy, the de‐aromatized Me‐PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P‐pincer nickel complexes.
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ISSN:0009-4536
2192-6549
DOI:10.1002/jccs.201700205