Removal of Cd2+, Cu2+, Ni2+, and Pb2+ ions from aqueous solutions using tururi fibers as an adsorbent

• Published in: Journal of applied polymer science Vol. 131; no. 20
• Main Authors: Melo, Diego Q., Vidal, Carla B., da Silva, André Leandro, Teixeira, Raimundo N. P., Raulino, Giselle Santiago Cabral, Medeiros, Thiago C., Fechine, Pierre B. A., Mazzeto, Selma Elaine, De Keukeleire, Denis, Nascimento, Ronaldo F.
• Format: Journal Article
• Language: English
• Published: Hoboken, NJ Blackwell Publishing Ltd 15.10.2014; Wiley; Wiley Subscription Services, Inc
• Subjects: adsorption; Agronomy. Soil science and plant productions; applications; Applied sciences; Biological and medical sciences; cellulose and other wood products; Exact sciences and technology; Fibers and threads; Forms of application and semi-finished materials; Fundamental and applied biological sciences. Psychology; General agronomy. Plant production; Industrial wastewaters; Materials science; Pollution; Polymer industry, paints, wood; Polymers; separation techniques; Technology of polymers; Use of agricultural and forest wastes. Biomass use, bioconversion; Wastewaters; Water treatment and pollution; Copper II; Monocotyledones; adsorption; separation techniques; Nickel II; Liquid solid adsorption; Adsorption isotherm; Adsorption capacity; Metal ion; Experimental study; Modeling; Kinetic model; Lead II; Cadmium II; cellulose and other wood products; Angiospermae; Spermatophyta; Kinetics; Palmae; Aqueous solution; Adsorbent; Factorial design; applications
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.40883

ABSTRACT This work investigates the removal of Cd2+, Cu2+, Ni2+, and Pb2+ ions from aqueous solutions using tururi fibers as an adsorbent under both batchwise and fixed‐bed conditions. It was found that modification of the tururi fibers with sodium hydroxide increased the adsorption efficiencies of all metal ions studied. The fractional factorial design showed that pH, adsorbent mass, agitation rate, and initial metal concentration influenced each metal adsorption differently. The kinetics showed that multi‐element adsorption equilibria were reached after 15 min following pseudo‐second‐order kinetics. The Langmuir, Freundlich, and Redlich–Peterson models were used to evaluate the adsorption capacities by tururi fibers. The Langmuir model was found to be suitable for all metal ions. Breakthrough curves revealed that saturation of the bed was reached in 160.0 mL with Cd2+ and Cu2+, and 52.0 mL with Ni2+ and Pb2+. The Thomas model was applied to the experimental data of breakthrough curves and represented the data well. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40883.