Electrospun carbon nanofiber-carbon nanotubes coated polyaniline composites with improved electrochemical properties for supercapacitors

• Published in: Electrochimica acta Vol. 259; p. 1110
• Main Authors: Agyemang, Frank Ofori, Tomboc, Gracita M, Kwofie, Samuel, Kim, Hern
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier BV 01.01.2018
• Subjects: Aniline; Capacitance; Carbon fibers; Carbon nanotubes; Carbonization; Component parts; Composite materials; Electrochemical analysis; Electrode materials; Electrodes; Nanofibers; Nanotubes; Physical chemistry; Polyacrylonitrile; Polyanilines; Polymer matrix composites; Supercapacitors
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2017.12.079

The carbon nanofiber-carbon nanotube (CNF-CNT) composites were fabricated by simple electrospinning and carbonization of polyacrylonitrile (PAN)-CNT solution prepared by first sonicating and stirring the CNT in N, N-dimethylformamide (DMF) as solvent. Aniline monomer was then coated on the composite materials via in situ chemical polymerization to form CNF-CNT-PANI composite. The as-prepared samples were then characterized. Importantly, the dispersed CNTs in the CNF-CNT composites were crucial for the CNF-CNTs acting as supports for the CNF-CNT-PANI composites to attain high electrochemical properties. The composite electrode material is found to be used as effective electrode material for supercapacitors with specific capacitance as high as 1119 F g−1 at 1 A g−1 compared to the bare CNF film with a specific capacitance of 278 F g−1. The composite electrode displaced excellent cyclic stability with retention of 98% even after 2000 cycles at a current density of 10 A g−1.