A Boron Dipyrromethene (BODIPY)-Based CuII-Bipyridine Complex for Highly Selective NO Detection

A BODIPY‐containing CuII–bipyridine complex for the simple selective fluorogenic detection of NO in air and in live cells is reported. The detection mechanism is based on NO‐promoted CuII to CuI reduction, followed by demetallation of the complex, which results in the clearly enhanced emission of th...

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Published inChemistry : a European journal Vol. 21; no. 44; pp. 15486 - 15490
Main Authors Juárez, L. Alberto, Barba-Bon, Andrea, Costero, Ana M., Martínez-Máñez, Ramón, Sancenón, Félix, Parra, Margarita, Gaviña, Pablo, Terencio, M. Carmen, Alcaraz, M. José
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 26.10.2015
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
BODIPY
cells
Chemistry
fluorescence
NO detection
quimiodosimeter
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Summary:A BODIPY‐containing CuII–bipyridine complex for the simple selective fluorogenic detection of NO in air and in live cells is reported. The detection mechanism is based on NO‐promoted CuII to CuI reduction, followed by demetallation of the complex, which results in the clearly enhanced emission of the boron dipyrromethene (BODIPY) unit. Cell chemistry: A boron dipyrromethene (BODIPY)‐containing CuII–bipyridine complex for the selective fluorogenic detection of NO in air and in live cells is reported (see scheme). The detection mechanism is based on NO‐promoted CuII to CuI reduction, followed by demetallation of the complex, which results in the enhanced emission of the BODIPY unit.
Bibliography:ark:/67375/WNG-0PQNL11V-7
European FEDER - No. MAT2012-38429-C04-01; No. MAT2012-38429-C04-02
Generalitat Valenciana - No. PROMETEOII/2014/047
DGICYT
istex:531268469FBD99430020A25BD9FDFFE6440FE78A
ArticleID:CHEM201502191
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201502191