Theoretical and experimental study of high-pressure synthesized B20-type compounds Mn1−x(Co,Rh)xGe

• Published in: Pure and applied chemistry Vol. 91; no. 6; pp. 941 - 955
• Main Authors: Chtchelkatchev, Nikolay M., Magnitskaya, Maria V., Sidorov, Vladimir A., Fomicheva, Ludmila N., Petrova, Alla E., Tsvyashchenko, Anatoly V.
• Format: Journal Article
• Language: English
• Published: Berlin De Gruyter 01.06.2019; Walter de Gruyter GmbH
• Subjects: Helices; high-pressure synthesis; HTMC-XVI; magnetic chiralities; Magnetic permeability; Magnetism; new materials; Orbitals; Phase diagrams; Synthesis
• ISSN: 0033-4545; 1365-3075
• DOI: 10.1515/pac-2018-1101

The search and exploration of new materials not found in nature is one of modern trends in pure and applied chemistry. In the present work, we report on experimental and density-functional study of the high-pressure-synthesized series of compounds Mn (Co,Rh) Ge. These high-pressure phases remain metastable at normal conditions, therewith they preserve their inherent noncentrosymmetric B20-type structure and chiral magnetism. Of particular interest in these two isovalent systems is the comparative analysis of the effect of 3 (Co) and 4 (Rh) substitution for Mn, since the 3 orbitals are characterized by higher localization and electron interaction than the 4 orbitals. The behavior of Mn (Co,Rh) Ge systems is traced as the concentration changes in the range 0 ≤   ≤ 1. We applied a sensitive experimental and theoretical technique which allowed to refine the shape of the temperature dependencies of magnetic susceptibility ) and thereby provide a new and detailed magnetic phase diagram of Mn Co Ge. It is shown that both systems exhibit a helical magnetic ordering that very strongly depends on the composition . However, the phase diagram of Mn Co Ge differs from that of Mn Rh Ge in that it is characterized by coexistence of two helices in particular regions of concentrations and temperatures.