Oxidative acylation of ,-diarylallylic alcohols: Synthesis of 1,2,4-triarylbutane-1,4-diones
A metal-free mediated oxidative acylation of ,-diarylallylic alcohols with simple aromatic aldehydes for the synthesis of 1,2,4-triphenylbutane-1,4-diones is presented. In the presence of TBPB (tert-butyl peroxybenzoate), desired products were obtained in good to excellent yields for 28 examples. Th...
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Published in | Applied organometallic chemistry Vol. 32; no. 8 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
HOBOKEN
Wiley
01.08.2018
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Subjects | |
Online Access | Get full text |
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Summary: | A metal-free mediated oxidative acylation of ,-diarylallylic alcohols with simple aromatic aldehydes for the synthesis of 1,2,4-triphenylbutane-1,4-diones is presented. In the presence of TBPB (tert-butyl peroxybenzoate), desired products were obtained in good to excellent yields for 28 examples. This protocol features high regioselectivity, wide functional group tolerance and atom economy. |
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ISSN: | 0268-2605 1099-0739 |
DOI: | 10.1002/aoc.4407 |