In₂Ge₆O₁₅(en)₂: A In-Ge Compound Composed of Germanate Layers Linked by Pillars of In₂O₆N₄ Double Octahedra

Two metals in one net: GeO4 tetrahedra and InO6N2 octahedra are primary building units in a new indium germanate. The germanium layers (yellow) are linked by the InO6N2 units (red) to form a 3D network. The compound is prepared by a hydrothermal synthesis using GeO2 and In(OH)3 in an aqueous solutio...

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Published inAngewandte Chemie (International ed.) Vol. 42; no. 36; pp. 4389 - 4391
Main Authors Pitzschke, Dragan, Bensch, Wolfgang
Format Journal Article
LanguageEnglish
Published Weinheim Wiley-VCH Verlag 22.09.2003
WILEY-VCH Verlag
WILEY‐VCH Verlag
Subjects
crystal structure
germanium
hydrothermal synthesis
indium
thermochemistry
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Summary:Two metals in one net: GeO4 tetrahedra and InO6N2 octahedra are primary building units in a new indium germanate. The germanium layers (yellow) are linked by the InO6N2 units (red) to form a 3D network. The compound is prepared by a hydrothermal synthesis using GeO2 and In(OH)3 in an aqueous solution of ethylenediamine.
Bibliography:http://dx.doi.org/10.1002/anie.200351115
ark:/67375/WNG-K23JG7LN-S
ArticleID:ANIE200351115
This work was supported by the State of Schleswig-Holstein and the Fonds der Chemischen Industrie. en=ethylenediamine.
istex:5B4DB4BC10D70C9B3F34E9F2022BA136783334C8
This work was supported by the State of Schleswig‐Holstein and the Fonds der Chemischen Industrie. en=ethylenediamine.
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200351115