5.07 - Molybdenum Compounds without CO or Isonitrile Ligands

This chapter discusses organometallic compounds that contain a direct metal–carbon bond and do not contain either a carbonyl or isonitrile ligand. It covers the complexes containing σ-bonded organic groups, and the alkylidene, alkylidyne, alkene, π-allyl, alkyne, cyclopentadienyl, and arene ligands....

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Published inComprehensive Organometallic Chemistry III, 13-Volume Set pp. 513 - 595
Main Author Flower, K.R.
Format Book Chapter
LanguageEnglish
Published Elsevier Ltd 2007
Elsevier
Subjects
Alkene
Alkyl
Alkylidene
Alkylidyne
Alkyne
Arene
Aryl
Biochemistry, Biology & Biotechnology
Biology & Microbiology
Chemistry & Chemical Engineering
Cyclopentadienyl
Molybdenum organometallic chemistry
Multiple bonds
Physical Chemistry
Review
Arene
Multiple bonds
Alkene
Cyclopentadienyl
Alkylidyne
Alkyl
Alkylidene
Molybdenum organometallic chemistry
Review
Aryl
Alkyne
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Summary:This chapter discusses organometallic compounds that contain a direct metal–carbon bond and do not contain either a carbonyl or isonitrile ligand. It covers the complexes containing σ-bonded organic groups, and the alkylidene, alkylidyne, alkene, π-allyl, alkyne, cyclopentadienyl, and arene ligands. The major emphasis of the discussion is on the synthesis of homoleptic alkyl complexes, C–H activation by well-defined cyclopentadienyl nitrosyl-containing complexes, the development of chiral alkylidene complexes and their use in metathesis chemistry, the development of well-defined alkylidyne metathesis catalysts, and the bioorganometallic chemisty of molybdenocene dichloride.
ISBN:9780080445908
9780080450476
008044590X
0080450474
DOI:10.1016/B0-08-045047-4/00072-8