Ion transport in LiI SiO 2 composites

The enhanced ionic conductivity observed when ceramic particles are added to LiI prompted this study of ionic transport along the LiI-SiO 2 interface. The results of a previous study of interfacial ion transport are reviewed and a possible mechanism for enhanced interfacial conduction is presented....

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Bibliographic Details
Published inSolid state ionics Vol. 9; pp. 123 - 130
Main Authors Phipps, J.B., Whitmore, D.H.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1983
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Summary:The enhanced ionic conductivity observed when ceramic particles are added to LiI prompted this study of ionic transport along the LiI-SiO 2 interface. The results of a previous study of interfacial ion transport are reviewed and a possible mechanism for enhanced interfacial conduction is presented. The effects of interfacial roughness, aliovalent doping (MgI 2) and homovalent doping (KI) of LiI on the LiI SiO 2 interfacial conductivity are discussed. It is concluded that the enhanced conductivity observed for LiI-ceramic particle composites results from rapid ion transport along the core of the interfacial region.
ISSN:0167-2738
1872-7689
DOI:10.1016/0167-2738(83)90220-5