Novel preconcentration technique for on-line coupling to high-speed narrow-bore capillary gas chromatography: sample enrichment by equilibrium (ab)sorption: II. Coupling to a portable micro gas chromatograph

• Published in: Journal of Chromatography A Vol. 791; no. 1; pp. 187 - 195
• Main Authors: Tuan, Hai Pham, Janssen, Hans-Gerd, Cramers, Carel A, Mussche, Phillippe, Lips, Jürgen, Wilson, Nigel, Handley, Alan
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 12.12.1997; Elsevier
• Subjects: Absorption; Alkanes; Alkanes - analysis; Alkanes - chemistry; Analysis methods; Analytical chemistry; Applied sciences; Atmospheric pollution; Benzene - analysis; Benzene - chemistry; Chemistry; Chromatographic methods and physical methods associated with chromatography; Chromatography, Gas - instrumentation; Chromatography, Gas - methods; Exact sciences and technology; Gas chromatographic methods; Heptanes - analysis; Heptanes - chemistry; Online Systems; Pentanes - analysis; Pentanes - chemistry; Pollution; Time Factors; Toluene - analysis; Toluene - chemistry; Volatilization; Trace analysis; Sample enrichment; Preconcentration; Equilibrium absorption; Alkanes; Gas chromatography; Hydrocarbon; Alkane; Microequipment; Portable equipment; Volatile organic compound; Air; Experimental study; Chemical enrichment
• ISSN: 0021-9673
• DOI: 10.1016/S0021-9673(97)00770-X

The technique of equilibrium (ab)sorption has been proven to be a powerful method for preconcentration of gaseous samples for high-speed narrow-bore capillary gas chromatography (GC) in general and field-portable GC instruments, often referred as micro GCs, in particular. Using a simple experimental set-up equipped with the open-tubular enrichment column it is possible to produce a homogeneously enriched sample plug, allowing reproducible injections of an enriched sample into the micro GC. Using a non-polar trapping column enrichment factors found for n-alkanes in the range of C 7 to C 10 ranged from 15 to 150 and agree well with calculated values. Using a highly retentive Thermocap column, the enrichment factor observed for heptane was above 500. As the use of this new preconcentration method requires only minimum modification of the micro GC, the chromatographic performance of the instrument was not compromised by direct coupling to the preconcentration device. Examples of on-line enrichment with portable micro GC analysis of VOCs from air are shown. These examples clearly demonstrate the potentials of the new method in field analysis.