Sb-loaded MnOx/TiO2/CNTs catalysts for selective catalytic reduction of NOx: insight to the SO2 and H2O tolerance

• Published in: Aircraft engineering Vol. 96; no. 5; pp. 747 - 755
• Main Authors: Natarajan, S., S., Raja, K., Pitchandi, Loganathan, Sivachandiran
• Format: Journal Article
• Language: English
• Published: Bradford Emerald Publishing Limited 09.07.2024; Emerald Group Publishing Limited
• Subjects: Adsorption; Ammonia; Antimony; Carbon nanotubes; Catalysts; Catalytic oxidation; Chemical reduction; Chemical synthesis; Efficiency; Flue gas; Manganese; Metal oxides; Poisoning; Selective catalytic reduction; Spectrum analysis; Sulfation; Sulfur dioxide; Temperature; Thermal resistance; Thermal stability; Titanium dioxide; SCR; NOx removal; Mn/TiO; Carbon nanotubes; SO; tolerance; Sb
• ISSN: 1748-8842; 1758-4213
• DOI: 10.1108/AEAT-11-2023-0299

Purpose This paper aims to synthesize and test Mn-Sb/TiO2-CNT catalysts with different Sb/Mn molar ratios to be used in NH3-SCR reaction. Design/methodology/approach A series of Sb-loaded carbon nanotubes (CNTs)-based Mn/TiO2 catalysts were prepared by the incipient wetness co-impregnation method and tested for the selective catalytic reduction (SCR) of NOx with NH3. Findings The Sb-loaded Mn/TiO2-CNTs catalyst outperformed other catalysts and presented the highest activity in the temperature regime of 100–400°C. The catalyst loaded with Sb also showed good SO2 and H2O resistance and exhibited better thermal stability. A stepwise study of SO2 addition evidenced that Mn-Sb/TiO2-CNTs catalyst exhibited better SO2 resistance than the base catalyst Mn/TiO2, where the Sb doping greatly inhibited the sulphating of active phase of the catalyst. Originality/value In Sb-loaded catalysts, the formed SOx species fused with SbOx instead of MnOx. This favoured interaction of SO2 with SbOx successfully prevents the MnOx from being sulphated by SO2 which substantially improves the SO2 tolerance of Sb-loaded catalysts.