A mixed-valence complex of platinum and thiourea: Spectroscopic ( 195Pt NMR, visible, esca) evidence

The results of NMR, UV and X-ray photoeletron speetroseopic measurements carried out on a complex of the type PtA 2Cl 3 (A = thiourea) are reported. These studies demonstrate that it is a mixed-oxidation-state complex, [Pt IIA 4] [Pt IVCl 6], and it is believed that it contains chains, · Pt II · Cl-...

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Published inChemical physics letters Vol. 76; no. 3; pp. 548 - 552
Main Authors Arrizabalaga, Ph, Castan, P., Laurent, J.-P., Salesse, A.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.01.1980
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Summary:The results of NMR, UV and X-ray photoeletron speetroseopic measurements carried out on a complex of the type PtA 2Cl 3 (A = thiourea) are reported. These studies demonstrate that it is a mixed-oxidation-state complex, [Pt IIA 4] [Pt IVCl 6], and it is believed that it contains chains, · Pt II · Cl-Pt IV- · Pt II.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(80)80665-8