Effect of Niobium on Microstructure and Properties of the CoCrFeNbxNi High Entropy Alloys

• Published in: Journal of materials science & technology Vol. 33; no. 7; pp. 712 - 717
• Main Authors: Jiang, Hui, Jiang, Li, Qiao, Dongxu, Lu, Yiping, Wang, Tongmin, Cao, Zhiqiang, Li, Tingju
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.07.2017
• Subjects: Alloy design; Mechanical properties; Microstructure; Wear resistance; Mechanical properties; Wear resistance; Microstructure; Alloy design
• ISSN: 1005-0302; 1941-1162
• DOI: 10.1016/j.jmst.2016.09.016

A series of CoCrFeNbxNi (x values in molar ratio, x=0, 0.25, 0.45, 0.5, 0.75, 1.0 and 1.2) high entropy alloys (HEAs) was prepared to investigate the alloying effect of Nb on the microstructures and mechanical properties. The results indicate that the prepared CoCrFeNbxNi (x>0) HEAs consist of a simple FCC solid solution phase and a Laves phase. The microstructures of the alloys change from an initial single-phase FCC solid solution structure (x=0) to a hypoeutectic microstructure (x=0.25), then to a full eutectic microstructure (x=0.45) and finally to a hypereutectic microstructure (0.5<x<1.2). The compressive test results show that the Nb0.45 (x=0.45) alloy with a full eutectic microstructure possesses the highest compressive fracture strength of 2558MPa and a fracture strain of 27.9%. The CoCrFeNi alloy exhibits an excellent compressive ductility, which can reach 50% height reduction without fracture. The Nb0.25 alloy with a hypoeutectic structure exhibits a larger plastic strain of 34.8%. With the increase of Nb content, increased hard/brittle Laves phase leads to a decrease of the plasticity and increases of the Vickers hardness and the wear resistance. The wear mass loss, width and depth of wear scar of the Nb1.2 (x=1.2) alloy with a hypereutectic structure are the lowest among all alloy systems, indicating that the wear resistance of the Nb1.2 alloy is the best one.