Influence of the indium concentration on microstructural and electrical properties of proton conducting NiO–BaCe0.9−xInxY0.1O3−δ cermet anodes for IT-SOFC application

• Published in: Journal of alloys and compounds Vol. 563; pp. 254 - 260
• Main Authors: Zunic, Milan, Brankovic, Goran, Foschini, Cesar Renato, Cilense, Mario, Longo, Elson, Varela, José Arana
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 25.06.2013; Elsevier
• Subjects: Anode; Applied sciences; Cermet; Condensed matter: structure, mechanical and thermal properties; Diffusion in solids; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Exact sciences and technology; Fuel cells; Physics; Protonic conductor; Self-diffusion and ionic conduction in nonmetals; Transport properties of condensed matter (nonelectronic); Protonic conductor; Anode; Cermet; Fuel cells; Electrical conductivity; Electrical properties; Chemical stability; Doping; Ionic conductors; Operating mode; Evaporation; Indium; Dispersive spectrometry; Optimization; Operating conditions; Quantity ratio; Sintering; Proton conductivity; Percolation; Microstructure; Anodes; X-ray diffraction analysis; Electrical characteristic
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2013.02.122

► The influence of indium concentration on anode properties was investigated. ► The cermet anode powders were obtained without any undesirable phases. ► Anode substrates were tested on chemical stability in the CO2 atmosphere. ► Conductivity measurements confirmed percolation through Ni grains. ► Fuel cell tests confirmed functionality of anode substrates. Optimization of the major properties of anodes based on proton conductors, such as microstructure, conductivity and chemical stability, is yet to be achieved. In this study we investigated the influence of indium on the chemical stability, microstructural and electrical characteristics of proton conducting NiO–BaCe0.9−xInxY0.1O3−δ (NiO–BCIYx) anodes. Four compositions of cermet anode substrates NiO–BCIYx were prepared using the method of evaporation and decomposition of solutions and suspensions (EDSS). Sintered anode substrates were reduced and their microstructural and electrical properties were examined before and after reduction as a function of the amount of indium. Anode substrates tested on chemical stability in the CO2 atmosphere showed high stability compared to anode substrates based on commonly used doped barium cerates. Microstructural properties of the anode pellets before and after testing in CO2 were investigated using X-ray diffraction analysis. Impedance spectroscopy measurements were used for evaluation of electrical properties of the anode pellets and the conductivity values of reduced anodes of more than 14Scm−1 at 600°C confirmed percolations through Ni particles. Under fuel cell operating conditions, the cell with a Ni–BCIY20 anode achieved the highest performance, demonstrating a peak power density 223mW/cm2 at 700°C confirming the functionality of Ni–BCIY anodes.