Charge-discharge performance of Na2/3Fe1/3Mn2/3O2 positive electrode in an ionic liquid electrolyte at 90°C for sodium secondary batteries

• Published in: Electrochimica acta Vol. 231; pp. 412 - 416
• Main Authors: Ding, Changsheng, Nohira, Toshiyuki, Hagiwara, Rika
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 20.03.2017
• Subjects: Charge-discharge performance; Ionic liquid electrolyte; Na2/3Fe1/3Mn2/3O2; Positive electrode; Sodium secondary battery; Charge-discharge performance; Positive electrode; Sodium secondary battery; Na2/3Fe1/3Mn2/3O2; Ionic liquid electrolyte
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2017.02.069

Ionic liquid is a promising electrolyte for sodium secondary batteries because of its negligible volatility, low flammability, and high thermal and electrochemical stabilities. In this study, Na2/3Fe1/3Mn2/3O2 as a positive electrode material was synthesized by a solid-state reaction, and its charge-discharge performance was investigated at 90°C in the ionic liquid electrolyte Na[FSA]-[C3C1pyrr][FSA] (FSA=bis(fluorosulfonyl)amide;C3C1pyrr=N-methyl-N-propylpyrrolidinium). The Na2/3Fe1/3Mn2/3O2 positive electrode delivered an initial discharge capacity of 227mAhg−1 at a current rate of 20mAg−1 in the voltage range of 2.0–4.3V. This study is the first where the Na2/3Fe1/3Mn2/3O2 positive electrode demonstrated a high reversible discharge capacity, larger than 220mAhg−1, due to the high operation temperature in the ionic liquid electrolyte.