Trimethylsilylated N-alkyl-substituted carbamates : II. Alcoholysis of trimethylsilyl N,N-dimethylcarbamate

The reaction of trimethylsilyl N,N-dimethylcarbamate with the sterically hindered alcohol 2-methylbutan-2-ol has been studied kinetically. The reaction shows autocatalytic character, and an equation has been derived which satisfactorily describes the kinetic behaviour. A mechanism is suggested for t...

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Published inJournal of organometallic chemistry Vol. 268; no. 3; pp. 207 - 211
Main Authors Knausz, Dezsö, Meszticzky, Aranka, Szakács, László, Csákvári, Béla
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 26.06.1984
Elsevier Science
Subjects
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
Alcoholysis
Temperature
Aliphatic compound
Medium effect
Tertiary alcohol
Silicon Organic compounds
Saturated compound
Urethane
Autocatalysis
Rate constant
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Abstract The reaction of trimethylsilyl N,N-dimethylcarbamate with the sterically hindered alcohol 2-methylbutan-2-ol has been studied kinetically. The reaction shows autocatalytic character, and an equation has been derived which satisfactorily describes the kinetic behaviour. A mechanism is suggested for the reaction.
AbstractList The reaction of trimethylsilyl N,N-dimethylcarbamate with the sterically hindered alcohol 2-methylbutan-2-ol has been studied kinetically. The reaction shows autocatalytic character, and an equation has been derived which satisfactorily describes the kinetic behaviour. A mechanism is suggested for the reaction.
Author Knausz, Dezsö
Szakács, László
Csákvári, Béla
Meszticzky, Aranka
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Issue 3
Keywords Alcoholysis
Temperature
Aliphatic compound
Medium effect
Tertiary alcohol
Silicon Organic compounds
Saturated compound
Urethane
Autocatalysis
Rate constant
Language English
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References Langer, Connell, Wender (BIB6) 1958; 23
Ismail (BIB8) 1963; 18
Froment, Bischoff (BIB12) 1979
Sommer, Citron (BIB11) 1967; 89
Bassindale, Eaborn, Wallon (BIB7) 1970; 25
Bassindale, Eaborn, Walton (BIB9) 1972; Organomet. Chem., 43
Valko, Ermakova, Vajda (BIB13) 1980; 8
Eaborn (BIB2) 1960
Pierce (BIB3) 1968
Kaufmann, Mann, Rühlmann, Kaufmann, Mann, Rühlmann (BIB10) 1965; 5
Mason, Smith (BIB5) 1966; 4
Knausz, Meszticzky, Szakács, Ujszászy, Csákvári (BIB1) 1983; 256
Fessenden, Crowe (BIB4) 1961; 26
References_xml – volume: 8
  start-page: 437
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– year: 1968
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  publication-title: Silylation of Organic Compounds
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– volume: 25
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  ident: BIB7
  publication-title: J. Organomet. Chem.
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Snippet The reaction of trimethylsilyl N,N-dimethylcarbamate with the sterically hindered alcohol 2-methylbutan-2-ol has been studied kinetically. The reaction shows...
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SubjectTerms Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
Title Trimethylsilylated N-alkyl-substituted carbamates : II. Alcoholysis of trimethylsilyl N,N-dimethylcarbamate
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Volume 268
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