Trimethylsilylated N-alkyl-substituted carbamates : II. Alcoholysis of trimethylsilyl N,N-dimethylcarbamate

The reaction of trimethylsilyl N,N-dimethylcarbamate with the sterically hindered alcohol 2-methylbutan-2-ol has been studied kinetically. The reaction shows autocatalytic character, and an equation has been derived which satisfactorily describes the kinetic behaviour. A mechanism is suggested for t...

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 268; no. 3; pp. 207 - 211
Main Authors Knausz, Dezsö, Meszticzky, Aranka, Szakács, László, Csákvári, Béla
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 26.06.1984
Elsevier Science
Subjects
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
Alcoholysis
Temperature
Aliphatic compound
Medium effect
Tertiary alcohol
Silicon Organic compounds
Saturated compound
Urethane
Autocatalysis
Rate constant
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Summary:The reaction of trimethylsilyl N,N-dimethylcarbamate with the sterically hindered alcohol 2-methylbutan-2-ol has been studied kinetically. The reaction shows autocatalytic character, and an equation has been derived which satisfactorily describes the kinetic behaviour. A mechanism is suggested for the reaction.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(84)80255-7