Studies on organosilicon chemistry: CXXII. Reaction of 2-oxiranylallylsilanes with acetals. Direct introduction of a vinyloxirane moiety

Direct 2-oxiranylallylation to acetals can be attained using 2-oxiranyl-2-propenyltrimethylsilanes. These are a new type of nucleophiles incorporating a vinyloxirane moiety as an electrophilic functionality.

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 473; no. 1; pp. C1 - C2
Main Authors Hojo, Makoto, Ishibashi, Naruyasu, Ohsumi, Katsufumi, Miura, Katsukiyo, Hosomi, Akira
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 28.06.1994
Elsevier Science
Subjects
Acetal
Allylation
Allylsilane
Chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Organic chemistry
Preparations and properties
Silane
Vinyloxirane
Acetal
Allylsilane
Silane
Vinyloxirane
Allylation
Ether
Aliphatic compound
Silicon Organic compounds
Epoxide
Three membered ring
Organic silane
Acid catalysis
Oxygen heterocycle
Titanium IV Chlorides
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Summary:Direct 2-oxiranylallylation to acetals can be attained using 2-oxiranyl-2-propenyltrimethylsilanes. These are a new type of nucleophiles incorporating a vinyloxirane moiety as an electrophilic functionality.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(94)80139-8