η 5-Pentadienyltricarbonylmanganese, an “open” analog of cymantrene

2,4-Pentadienyltrimethyltin, obtained by the reaction of pentadienyllithium with trimethyltin chloride, reacted with bromopentacarbonylmanganese in refluxing tetrahydrofuran to give η 5-pentadienyltricarbonylmanganese in 52% yield.

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 208; no. 2; pp. 189 - 193
Main Authors Seyferth, Dietmar, Goldman, Emma W., Pornet, Jacques
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1981
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Summary:2,4-Pentadienyltrimethyltin, obtained by the reaction of pentadienyllithium with trimethyltin chloride, reacted with bromopentacarbonylmanganese in refluxing tetrahydrofuran to give η 5-pentadienyltricarbonylmanganese in 52% yield.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)82674-1