Generation of C 60 radical cation and radical adduct of dichloro- or monochloromethyl radical to C 60: Pulse radiolysis and laser photolysis of C 60 in polar chloromethane

The radical cation of C 60 is generated either via hole transfer from the radical cation of polar chlorinated methane to C 60 or via electron transfer from the triplet of C 60 to electrophilic polar chlorinated methane. The radical adducts CHCl 2 and CH 2Cl of C 60 were produced via a similar mechan...

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Bibliographic Details
Published inRadiation Physics and Chemistry Vol. 50; no. 3; pp. 245 - 247
Main Authors Lian, Z.R., Yao, S.D., Lin, W.Z., Wang, W.F., Lin, N.Y.
Format Book Review
LanguageEnglish
Published Elsevier Ltd 01.09.1997
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Summary:The radical cation of C 60 is generated either via hole transfer from the radical cation of polar chlorinated methane to C 60 or via electron transfer from the triplet of C 60 to electrophilic polar chlorinated methane. The radical adducts CHCl 2 and CH 2Cl of C 60 were produced via a similar mechanism to the generation of the radical adduct [C 60-CCl 3] in CCl 4.
ISSN:0969-806X
1879-0895
DOI:10.1016/S0969-806X(97)00020-0