Sensitivity of phosphorus introduction stage to the catalytic activity of CeO2/TiO2 catalysts for selective catalytic reduction of NOx with NH3

• Published in: Applied surface science Vol. 698
• Main Authors: Yu, Shibo, Zeng, Yiqing, Zhan, Mengna, Zhang, Shule, Zhong, Zhaoxiang
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 30.07.2025
• Subjects: CeO2/TiO2; NH3-SCR; Phosphorus modification; Preparation process; Preparation process; Phosphorus modification; NH3-SCR; CeO2/TiO2
• ISSN: 0169-4332
• DOI: 10.1016/j.apsusc.2025.163075

[Display omitted] •Revealing the critical effect of P introduction stage on catalyst performance.•The stage of P introduction determines the distribution of P in catalyst.•The distribution of P in catalyst structure determines the catalyst performance. The influence of phosphorus (P) on ammonia selective catalytic reduction (NH3-SCR) catalysts has been the subject of considerable scrutiny. Nevertheless, the precise mechanism of its influence remains a matter of contention. Furthermore, the impact of introducing P at varying stages during catalyst preparation process and its different sites within the catalyst structure on performance is frequently disregarded, significantly hindering practical guidance for designing effective modified catalysts. In this study, a series of P-modified CeO2/TiO2 catalysts were synthesized by introducing P at different preparation stages, and various of characterization and comparison experiments were conducted to elucidate the effect of introducing P at different stages on NH3-SCR performance of NOx. Results show that introducing P before loading CeO2 boosts catalyst activity, whereas delaying the introduction of P results in decreased activity and a progressive decline in catalyst performance as the sequence of P introduction is postponed. P introduced earlier tends to be distributed on the surface of the TiO2 support, which contributes to the dispersion and anchoring of Ce species. In contrast, when the introduction of P was delayed, it tended to be distributed on the surface of the active species, which led to pore plugging and active sites being covered. Secondly, the variation in loading sites resulting from alterations in the stage of P introduction significantly affected on the chemical environment of Ce species, leading to notable differences in the redox capacity of the catalysts. This is the primary reason for the considerable discrepancy in the SCR performance of the catalysts. This study revealed the sensitivity of the stage of P introduction to CeO2/TiO2 catalysts, providing new insights for designing modified CeO2/TiO2 catalysts.