Synthesis and some reactions of the stable vinyl cation stabilized by the 3-η 5-cyclopentadienyl-η 5-(3)-1,2-dicarbollyliron(II)-1 group

An individual vinyl cation in the form of a zwitterion stabilized by the 3-η 5-C 5H 5Fe 11-η 5-(3)-1,2-C 2B 9 H 10-1 group has been produced for the first time, and its reactions with nucleophilic agents have been studied. Deprotonation yielding an acetylene derivative is the main reaction in the in...

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 270; no. 2; pp. 229 - 235
Main Authors Zakharkin, L.I., Kobak, V.V.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1984
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Summary:An individual vinyl cation in the form of a zwitterion stabilized by the 3-η 5-C 5H 5Fe 11-η 5-(3)-1,2-C 2B 9 H 10-1 group has been produced for the first time, and its reactions with nucleophilic agents have been studied. Deprotonation yielding an acetylene derivative is the main reaction in the interaction of the vinyl cation with MeLi, NaBH 4 and C 5H 5N.
ISSN:0022-328X
1872-8561
DOI:10.1016/0022-328X(84)80363-0