Synthesis and some reactions of the stable vinyl cation stabilized by the 3-η 5-cyclopentadienyl-η 5-(3)-1,2-dicarbollyliron(II)-1 group
An individual vinyl cation in the form of a zwitterion stabilized by the 3-η 5-C 5H 5Fe 11-η 5-(3)-1,2-C 2B 9 H 10-1 group has been produced for the first time, and its reactions with nucleophilic agents have been studied. Deprotonation yielding an acetylene derivative is the main reaction in the in...
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Published in | Journal of organometallic chemistry Vol. 270; no. 2; pp. 229 - 235 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
1984
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Online Access | Get full text |
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Summary: | An individual vinyl cation in the form of a zwitterion stabilized by the 3-η
5-C
5H
5Fe
11-η
5-(3)-1,2-C
2B
9
H
10-1 group has been produced for the first time, and its reactions with nucleophilic agents have been studied. Deprotonation yielding an acetylene derivative is the main reaction in the interaction of the vinyl cation with MeLi, NaBH
4 and C
5H
5N. |
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ISSN: | 0022-328X 1872-8561 |
DOI: | 10.1016/0022-328X(84)80363-0 |