Chiral tridentate C 2 diphosphine ligands for enantioselective catalysis

We describe the synthesis of four ligands of a family of tridentate diphosphine ligands possessing C 2 symmetric chirality for use in transition metal complex asymmetric catalysis. The synthesis of four ligands of a family of tridentate diphosphine ligands with a PNP donor set possessing C 2 symmetr...

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Bibliographic Details
Published inTetrahedron letters Vol. 37; no. 28; pp. 4933 - 4936
Main Authors Sablong, Rafaël, Newton, Claire, Dierkes, Peter, Osborn, John A.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 08.07.1996
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
BAKERS-YEAST
BETA-KETO-ESTERS
ASYMMETRIC HYDROGENATION
MICROBIAL REDUCTION
STEREOCHEMICAL CONTROL
COMPLEXES
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Summary:We describe the synthesis of four ligands of a family of tridentate diphosphine ligands possessing C 2 symmetric chirality for use in transition metal complex asymmetric catalysis. The synthesis of four ligands of a family of tridentate diphosphine ligands with a PNP donor set possessing C 2 symmetric chirality are reported.
ISSN:0040-4039
1873-3581
DOI:10.1016/0040-4039(96)00968-9