Massenspektroskopishce untersuchungen an olefin-isonitril-eisendicarbonyl-komplexen

The mass spectra of the isonitrile complexes oleneFe(CO) 2CNL (olene, see Table 1, L = Me, Et, SiMe 3, SnMe 3) are summarized and a comparative discussion is given. Whilst the successive loss of CO and the elimination of the intact isonitrile or olefin ligands are similar processes for all compounds...

Full description

Saved in:
Bibliographic Details
Published inJournal of organometallic chemistry Vol. 191; no. 1; pp. 205 - 215
Main Authors Merbach, Peter, Würstl, Peter, Seibold, Hans-Jürgen, Popp, Werner
Format Journal Article
LanguageGerman
Published Elsevier B.V 27.05.1980
Online AccessGet full text

Cover

More Information
Summary:The mass spectra of the isonitrile complexes oleneFe(CO) 2CNL (olene, see Table 1, L = Me, Et, SiMe 3, SnMe 3) are summarized and a comparative discussion is given. Whilst the successive loss of CO and the elimination of the intact isonitrile or olefin ligands are similar processes for all compounds, there are important differences in the fragmentations of the complexes olefin ligands, which are therefore noteworthy. Die Massenspektren der Isonitrilkomplexe olenFe(CO) 2CNL (olen, L: siehe Tab. 1) werden tabellarisch zusammengesfasst und vergleichend diskutiert. Während kie sukzessive Abspaltung von CO sowie die Eliminierung der intakten Isonitril- order Olefin-Liganden allen Verbindungen gemeinsam sind, weichen die Abbauprozesse der komplex gebundenen Olefinliganden erheblich voneinander ab und sind daher von besonderem Interesse.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)88568-X