Heterogeneous reactions : III. Evidence for an alkoxide induced 1,2-hydride shift from silicon to carbon under heterogeneous gas/solid phase reaction

• Published in: Journal of organometallic chemistry Vol. 134; no. 2; pp. 173 - 180
• Main Authors: Hopper, Steven P., Tremelling, Michael J., Ginsberg, Robert J., Mendelowitz, Paul C.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 12.07.1977

The interaction of solid alkoxide bases with chloromethyldialkylsilanes leads to the formation of products which may be formulated as arising via a 1,2-hydride shift from silicon to carbon. Other mechanisms for the formation of the rearranged product are considered and evidence for an intramolecular...