Heterogeneous reactions : III. Evidence for an alkoxide induced 1,2-hydride shift from silicon to carbon under heterogeneous gas/solid phase reaction

The interaction of solid alkoxide bases with chloromethyldialkylsilanes leads to the formation of products which may be formulated as arising via a 1,2-hydride shift from silicon to carbon. Other mechanisms for the formation of the rearranged product are considered and evidence for an intramolecular...

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Published inJournal of organometallic chemistry Vol. 134; no. 2; pp. 173 - 180
Main Authors Hopper, Steven P., Tremelling, Michael J., Ginsberg, Robert J., Mendelowitz, Paul C.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 12.07.1977
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Summary:The interaction of solid alkoxide bases with chloromethyldialkylsilanes leads to the formation of products which may be formulated as arising via a 1,2-hydride shift from silicon to carbon. Other mechanisms for the formation of the rearranged product are considered and evidence for an intramolecular process is presented. The syntheses of chloromethyldimethyldeuteriosilane, chloromethyldiethylsilane and t-butoxydiethylmethylsilane are described.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)81417-5