Numerical analysis of zero-carbon HCCI engine fuelled with steam diluted H2/H2O2 blends

• Published in: Fuel (Guildford) Vol. 326
• Main Authors: Fernie, Oliver, Megaritis, Thanos, Ganippa, Lionel Christopher, Tingas, Efstathios-Al
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.10.2022
• Subjects: HCCI; Heavy duty engine; Hydrogen; Hydrogen peroxide; Ignition promoter; NOx; HCCI; Heavy duty engine; Hydrogen peroxide; Ignition promoter; Hydrogen; NOx
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2022.125100

The addition of hydrogen peroxide and steam to a hydrogen-fuelled HCCI engine was investigated at various fuel lean conditions (ϕeff = 0.2–0.6) and compression ratios (15–20) using a 0-dimensional numerical model. The use of hydrogen peroxide as an ignition promoter demonstrated increased IMEP (16%–39%), thermal efficiency (up to 2%), and reduced NOx (50%–76%) when compared to the conventional method of intake charge heating. When hydrogen peroxide was used as an ignition promoter, a 15% addition of steam was sufficient to reduce NOx by 93%–97%, though this reduced IMEP and thermal efficiency slightly. When heat transfer was considered and steam addition was increased from 0%–10%, no increase in intake air heating was able to match the IMEP of 5% hydrogen peroxide addition without an increase in the equivalence ratio (up to 40%). The parametric space of hydrogen peroxide (0%–25%) and steam (0%–40%) addition was explored in view of engine performance metrics, showing the complete range of conditions possible through control of both inputs. A three-order reduction in NOx was possible through steam addition. An optimal balance of performance and emissions occurred at 5%–10% hydrogen peroxide and 10%–15% steam addition. In a study of compression ratio, very little hydrogen peroxide addition (<5%) was required to achieve 98% of the maximum efficiency at higher compression ratios (19–20), though at lower compression ratios (<17) impractical quantities of hydrogen peroxide were required. The 10% steam addition present at these conditions led to extremely low NOx levels for ϕeff of 0.3 and 0.4, though at ϕeff of 0.5 NOx levels would require some after-treatment. Maintaining constant a high or low load across steam additions was possible through reasonable adjustment of hydrogen peroxide addition. •Hydrogen Peroxide increased performance, lowered emissions of Hydrogen HCCI engine.•Three-order reduction of NOx possible through additional steam dilution.•Hydrogen Peroxide was preferable ignition promoter compared to glow plug method.•No exhaust treatment necessary at lean equivalence ratios.•5%–10% Hydrogen Peroxide and 10%–15% steam dilution ideal for most conditions.